Ce travail consist??? ??? synth???tiser et ??? ???tudier la structure ???lectronique de deux types de mol???cules: les "acrylonitriles h???t???rosubstitu???s," les "h???t???roalc???nes" par la UV-SPE. La synth???se des mol???cules cibles a ???t??? faite par la Thermolyse Eclair et la R???action Gaz - Solide sous Vide. L'interpr???tation spectrale a ???t??? entreprise sur la base d'une approche quantique des potentiels d'ionisation. La 1re partie est l'???tude des "acrylonitriles h???t???rosubstitu???s" par les groupements ...
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Ce travail consist??? ??? synth???tiser et ??? ???tudier la structure ???lectronique de deux types de mol???cules: les "acrylonitriles h???t???rosubstitu???s," les "h???t???roalc???nes" par la UV-SPE. La synth???se des mol???cules cibles a ???t??? faite par la Thermolyse Eclair et la R???action Gaz - Solide sous Vide. L'interpr???tation spectrale a ???t??? entreprise sur la base d'une approche quantique des potentiels d'ionisation. La 1re partie est l'???tude des "acrylonitriles h???t???rosubstitu???s" par les groupements simples: NH2, OH, SH, etc. La plupart de ces compos???s sont thermodynamiquement instables. Leur caract???risation en phase condens???e a ???t??? conduite ??? basse temp???rature. La 2???me partie est consacr???e aux h???t???roalc???nes: iminenitriles et arsaalc???nes. La synth???se des iminenitriles a ???t??? effectu???e par d???composition thermique des az???tidines et des beta-lactames correspondants. Enfin, nous avons r???ussi la synth???se de la m???thylidynearsine, le plus simple des arsaalcynes, ainsi que sa caract???risation par UV-SPE et MS.
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Add this copy of Les Heterocomposes Primaires Alpha, Beta-Insatures to cart. $88.44, new condition, Sold by Ria Christie Books rated 4.0 out of 5 stars, ships from Uxbridge, MIDDLESEX, UNITED KINGDOM, published 2018 by Omniscriptum.
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