Cyclopeptide Alkaloids.- 1. Introduction.- 2. Classification.- 3. Structure Elucidation - Stereochemistry.- 3.1. NMR Spectroscopy.- 3.2. UV, IR, CD Spectroscopy.- 3.3. MS.- 4. MS Fragmentation of Cyclopeptide Alkaloids and Related Compounds.- 4.1. Fragmentation of 4(14)-Frangulanine- and -Integerrine-Type Cyclopeptide Alkaloids.- 4.2. Fragmentation of 4(14)-Pandamine-Type Cyclopeptide Alkaloids.- 4.3. Fragmentation of 5(13)-Zizyphine-A- and 5(14)-Amphibine-B-Type Cyclopeptide Alkaloids.- 4.4. Fragmentation of 5(14) ...
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Cyclopeptide Alkaloids.- 1. Introduction.- 2. Classification.- 3. Structure Elucidation - Stereochemistry.- 3.1. NMR Spectroscopy.- 3.2. UV, IR, CD Spectroscopy.- 3.3. MS.- 4. MS Fragmentation of Cyclopeptide Alkaloids and Related Compounds.- 4.1. Fragmentation of 4(14)-Frangulanine- and -Integerrine-Type Cyclopeptide Alkaloids.- 4.2. Fragmentation of 4(14)-Pandamine-Type Cyclopeptide Alkaloids.- 4.3. Fragmentation of 5(13)-Zizyphine-A- and 5(14)-Amphibine-B-Type Cyclopeptide Alkaloids.- 4.4. Fragmentation of 5(14)-Scutianine-A-Type Cyclopeptide Alkaloids (Hymenocardine included).- 4.5. Fragmentation of 4(14)-Amphibine-F-Type Cyclopeptide Alkaloids.- 4.6. Fragmentation of 4(13)-Nummularine-C-Type Cyclopeptide Alkaloids.- 4.7. Fragmentation of 4(15)-Mucronine-A-Type Cyclopeptide Alkaloids.- 4.8. Fragmentation of Linear Peptide Alkaloids.- 4.9. Fragmentation of Neutral Compounds Related to Cyclopeptide Alkaloids.- 4.10. Miscellaneous.- 4.11. Common Fragments.- 5. Identification Strategy.- 6. Physical and Spectral Data of Cyclopeptide Alkaloids and Related Compounds.- 7. Synthesis.- 8. Biological Activity.- 8.1. Sedative Activity.- 8.2. Antibacterial Activity.- 8.3. Antifungal Activity.- 9. Biosynthesis - Tissue Culture.- 10. Conclusions.- 11. General Tables.- Table 7. Cyclopeptide Alkaloids and Related Compounds in Order of Increasing Molecular Weight.- Table 8. Alphabetical List of Cyclopeptide Alkaloids and Related Compounds.- Table 9. Plant Index.- Addendum.- References.- Naturally Occurring 6-Substituted 5,6-Dihydro-?-Pyrones.- 1. Introduction.- 2. 6-Alkyl-5,6-dihydro-?-pyrones.- 3. 6-Alkenyl-5,6-dihydro-?-pyrones.- 4. 6-Aryl-5,6-dihydro-?-pyrones.- 5. Physical Methods of Structure Determination.- References.- Author Index.
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